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“With two equivalents of metallic sulphate to one equivalent of metallic sulphide, in the case of lead, according to the following equation:

 PbS + 2PbSO4 = 2PbO + Pb + 3SO2.

“With three equivalents of metallic sulphate to one of metallic sulphide, in the case of lead, according to the following equation:

 PbS + 3PbSO4 = 4PbO + 4SO2.”

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THE PREPARATION OF FINE MATERIAL FOR SMELTING

By T. J. Greenway

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(January 12, 1905)

In the course of smelting, at the works of the company known as the Broken Hill Proprietary Block 14, material which consisted chiefly of silver-lead concentrate and slime, resulting from the concentration of the Broken Hill complex sulphide ore, I had to contend with all the troubles which attend the treatment of large quantities of finely divided material in blast furnaces. With the view of avoiding these troubles, I experimented with various briquetting processes; and, after a number of more or less unsatisfactory experiences, I adopted a procedure similar to that followed in manufacturing ordinary bricks by what is known as the semi-dry brick-pressing process. This method of briquetting not only converts the finely divided material cheaply and effectively into hard semi-fused lumps, which are especially suitable for the heavy furnace burdens required by modern smelting practice, but also eliminates sulphur, arsenic, etc., to a great extent; therefore, it is capable of wide application in dealing with concentrate, slime, and other finely divided material containing lead, copper and the precious metals.

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