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The fire was either enclosed in hollow stones or iron vessels, and thrown from a catapult, or sometimes filled into the end of arrows and assisted to propel them forward or sustain their flight.

Philostratus (170–250 A.D.), writing of the Indian Campaign of Alexander the Great (B.C. 326), relates that the inhabitants of a town on the river Hyphasis (Beas) “defended themselves by means of lightning and thunder, which darted upon their besiegers.” This has been considered as evidence of the use of firearms, but is more probably the first reference to Greek-fire. Greek-fire or “naphtha” was used at the defence of Constantinople between 660 and 667.

At the siege of Pian-King Lo-Yang (1232), as mentioned in the Chinese Annals, iron pots were thrown containing a burning substance which could spread fire over half an acre, and described by the historians as the “thunder which shakes heaven.”

The Mongolians attacking Bagdad in the year 1258 made use of similar vessels, also fire arrows. Marco Polo, describing sieges of towns in China 1268 to 1273, mentions the throwing of fire.