Читать книгу A Practical Manual of the Collodion Process. Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper онлайн

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"In using the mixed acids, the limits are the nitric acid being too strong, in which case the product is insoluble, or too weak, when the cotton becomes immediately matted or even dissolved, if the mixture is warm. I have availed myself of these facts in order to produce collodion-wool by the use of acids, without the trouble of calculating the proper mixture according to their strength. Five parts by measure of sulphuric acid, and four of nitric acid of specific gravity not lower than 1·4, are mixed in an earthenware or thin glass vessel capable of standing heat; small portions of water are added gradually (by half drachms at a time, supposing two ounces to have been mixed,) testing after each addition by immersion of a small portion of cotton; the addition of water is continued until a fresh piece of cotton is found to contract and dissolve on immersing; when this takes place, add half the quantity of sulphuric acid previously used, and (if the temperature does not exceed 130°, in which case it must be allowed to cool to that point,) immerse as much cotton, well pulled out, as can be easily and perfectly soaked; it is to be left in for ten minutes, taking care that the mixture does not become cold, and then transferred to cold water, and thoroughly washed; this is a matter of much importance, and should be performed at first by changing the water many times, until it ceases to taste acid, and then treating it with boiling rain-water until the color of blue litmus remains unchanged; the freedom from all trace of acid is insured by adding a little ammonia before the last washing. Cotton thus prepared should dissolve perfectly and instantaneously in ether containing a little alcohol, without leaving a fibre behind, and the film it produces be of the greatest strength and transparency, being what M. Gaudin terms 'rich in gun-cotton.'